The hydrocracker unit was modeled with a commercial simulation program that has the capability to model reactors, heat exchangers, furnaces, columns, pipe segments and other equipment. The high naphthene content makes the hydrocracker gasoline an excellent feed for catalytic reforming, and good yields of highoctanenumber gasoline can be obtained. Aug 10, 2017 the feed to resid hydrocracker is crude unit vacuum bottoms. Some hydrocrackers produce mainly naphtha, whereas other units produce mainly middle distillates. Hydrocracking processes are designed for, and run at, a variety of conditions. Distillate hydrotreating in general, all liquid distillate streams contain sulfur compounds that must be removed saturate olefins in diesel to improve the cetanenumber hydrogenation at the high pressure produces small amounts of naphtha from hydrocracking required to get at the embedded sulfur. Isocracking hydrocracker designs include singlestage once through, singlestage recycle and twostage recycle processes. The hydrocracker yields a high volume of kerosene and light gasoil distillate. Am1525 new hydrocracking developments demonstrate lower. Optimising middle distillate production in a hydrocracker. Vgo, coker gas oils, and deasphalted oils to produce distillates, primarily ultralowsulfur diesel ulsd, kerosene, and naphtha for use. Uop is the world leading provider of distillate hydrotreating technology with more than 300 units licensed since the 1950s, including more than 50 units licensed in the last six years. In view of this, the design and operation of a hydrocracking unit has been studied for maximising the diesel fraction through optimisation of process parameters. Distillate hydrotreating hydrotreating processes aim at the removal of impurities such as sulfur and nitrogen from distillate fuelsnaphtha, kerosene, and dieselby treating the feed with hydrogen at elevated temperature and pressure in the presence of a catalyst.
Refiners interested in a new unit design will benefit from the same technology of high conversion distillate selective catalysts. Limits to how much fcc decant oil can be processed in a coker. Hydrocracking, processing heavy feedstocks to maximize. Hydrocracking is a catalytic chemical process used in petroleum refineries for converting the highboiling constituent hydrocarbons in petroleum crude oils to more valuable lowerboiling products such as gasoline, kerosene, jet fuel and diesel oil. The resulting product is a cleanburning diesel, jet fuel, and gasoline. Using aspentechs dmcplus and gcc inferential calculations, a middle distillate hydrocracker unit has been optimized. The hydrocracking process in a typical hydrocracker unit and a diesel hydrotreating unit is intricately covered with animation in the training module.
How to maximise middle distillate production and assure product quality from a range of. The profitability of the unit is related to the values of the different products from the hydrocracker. Another way to increase unit margin is to increase throughput, which also. Hydrotreating unit refinery plant petroleum refining.
Sep 17, 2017 the hydrocracking process in a typical hydrocracker unit and a diesel hydrotreating unit is intricately covered with animation in the training module. Hydrocracking catalyst and processing developments r efiners currently find themselves in a challenging environment as regulations continue to increase demands on refining processes, while highquality refining feedstocks become scarcer and consequently more expensive. This feed was hydrocracked to distillate at a conversion of over 95% in a. Abstract process economics program report 211a hydrocracking. However this comes at very high capital and operating costs. A hydrocracking unit takes heavy gas oil from the atmospheric tower, the. In a twostage hydrocracker unit, conversion in stages i and ii holds the key for controlling product yield pattern and quality. Hydrocracker unit process hcu diesel hydrotreating. The portfolio of base metal hydrocracking catalysts offered by topsoe is shown in figure 1. Processing heavier feed stocks poses many challenges to the hydrocracking unit.
However, if middle distillate, kerosene, diesel and jet fuel are to be. Hydrocracking is an important source of diesel and jet fuel today in. These gas oils are heavier than distillate fuel oil, and they have a higher. However, quality limitations have to be recognized feed to fcc. The hydrocracker cracks the heavy longchain molecules into shorter chain molecules in the presence of hydrogen and catalyst. Hydrocracking unit design hydroprocessing for clean energy. Over the last several years we have seen an increased demand for high quality distillate fuels and this is expected to continue over the next decade. The units designed at that time were mainly geared toward cracking distillate range material to naphtha for gasoline production. Hydrocracker unit after that, information specific to refineries in texas is described. Effects of cat and pressure on the yield pattern of a hydrocracker are discussed below.
With the broad use of several alloy materials, to ensure the installation of the correct material in the right place, a positive material identification pmi program is required. Hydrocracker unit process hcu diesel hydrotreating unit. It is well known that low activity hydrocracking catalysts have a high selectivity towards middle distillate production, whereas high activity hydrocracking catalysts exhibit a lower middle distillate selectivity. The unit has a design capacity of 80,000 bpsd and is built with two parallel reactor trains, each having capacity of 40,000 bpsd. A hydrocracking unit, or hydrocracker, takes gas oil, which is heavier and has a higher boiling range than distillate fuel oil, and cracks the heavy molecules into distillate and gasoline in the presence of hydrogen and a catalyst. This combination of increasing raw material cost usually of. Improved unit operations allows flexibility between gasoline and diesel production by maximizing yield cuts. When diesel selectivity is maintained through high conversion, the design of a unit will reflect that and substantial capex and opex savings can be achieved. Fresh feed is mixed with a heavy vacuum gas oil diluent. The design conversion is 77 wt % of the vacuum residuum. It is a highquality diesel blendstock, with low sulfur and high cetane. Mynah technologies, chesterfield, mo abstract the paper presents a case study on development and implementation of the operator training system for a greenfield hydrocracker unit at a large north american refinery. There are a good many different proprietary hydrocracker designs available under license. The combined feed enters surge drum v33, is pumped to feed heater h01 then mixed with highpressure recycled hydrogen gas, is preheated in h02 in mixers, then fed to the reactor v01 at about 750f and 2450 psig see figure 3.
A hydrotreater is sometimes used to pretreat the feed to a hydrocracker unit, or to process the naphtha and middles distillate stream from the atmospheric distillation unit. The first step of the simulation of a hydrocracker is the selection of an appropriate thermodynamics property package. Conversion in turn is controlled by varying cat andor reactor pressure. Middle distillate products are marketed as kerosene, jet fuel, diesel fuel and fuel oils. Uop has developed two stateoftheart hydrocracking catalysts to meet the refining industrys current and future need for quality middle distillate. Improving hydrocracker unit operations with the smart refinery the hydrocracker unit is an essential process for the overall refinery profitability in converting low value heavy feedstock into higher value fuels such as diesel and gasoline. Optimise hydrocracker operations for maximum distillates. Enhancing refinery profitability by gasification, hydroprocessing.
Hydrocracking processes distillate hydrocracking is a refining process for conversion of heavy gas oils and heavy diesels or similar boilingrange heavy distillates into light distillates naphtha, kerosene, diesel, etc. For each product, the value is related to the quality of the product. A hydrocracking unit, or hydrocracker, takes gas oil, which is heavier and has a higher boiling range than distillate fuel oil, and cracks the heavy. These gas oils are heavier than distillate fuel oil, and they have a higher boiling range as well. The optimized design depicted in figure 1515 recovers hydrogen from the two purge. New hydrocracking catalysts for high quality distillate.
The feed to resid hydrocracker is crude unit vacuum bottoms. It is a similar unit yielding a similar range and quality of products, but it is designed to handle heavier vacuum resid as a feed. Hydrocracking is a versatile catalytic refining process that upgrades petroleum feedstocks by adding hydrogen, removing impurities, and cracking to a desired boiling range. One of the catalysts, uop dhc8, is an amorphous catalyst that is characterized by high, stable yields of quality middle distillate products. Distillation is the process of separating the components or substances from a liquid mixture by using selective boiling and condensation. Optimization study in hydrocracker unit using simulation model.
Such a unit maximizes the yield of naphtha, jet fuel, or diesel depending on the recycle cut point used in the distillation section. The controller significantly reduces variations in the cutpoints of kerosene and diesel, allowing the unit to maximise production closer to the product specifications. A twostage hydrocracker with intermediate distillation represents the most common process configuration for maximizing middle distillates. Hydrocracking, processing heavy feedstocks to maximize high. The process consists of causing feed to react with. In gasoline production, for example, the hydrocracker product must be further processed in a catalytic reformer as it has a high naphthene content and relatively low octane number. The hydrocracker is a highpressure, moderate temperature conversion unit. Distillation may result in essentially complete separation nearly pure components, or it may be a partial separation that increases the concentration of selected components in the mixture.
Hydrocracked distillate this is a highquality diesel. The hydrocracker yields a high volume of kerosene and light gasoil of good quality high cetane and low sulfur. Most desired option is to send hcgo to hydrocracker. The flexiblity in the design and operation of hydrocrackers allows a wide range of feeds and of product yields. There are two main flow scheme configurations utilized for the reactor section design of hydrocracking units.
Safety and the installation of correct material go hand in hand in hydrocracker units. Our singlesource supply of all the key elements of a hydrocracking unit comprising hydrocracker pretreatment, hydrocracking and grading catalysts, technology licensing including heavy polynuclear aromatic hpna management solutions and highperformance reactor internals can help you maximize yields of the exact products you need whether. Pretreating of the hydrocracker feed is needed to protect the hydrocracker catalyst from various poisonous components. Thus hydrocracking becomes the technology of choice to address this market need. However if fcc bottoms is sent to the coking unit, this recycle could cause a buildup of refractory type material. Hydrocracker distillate is one of the key products from the hydrocracker. Therefore, an increase in middle distillate selectivity will further increase the operating margin of the hydrocracker. The hydrocracker is particularly valuable in a refinery that is trying to maximize diesel production and reduce residual fuel oil.
501 450 1546 381 326 1254 1161 466 756 487 641 450 785 1007 1187 530 318 536 78 694 461 120 869 478 1525 866 1253 1503 1545 1494 298 1403 940 1427 1303 835 1189 394 728 851 787 1312 496